(2) The book collection of Class 4, Grade 5: 6×39=234 (volumes),
(3) The total number of fifth-grade students:171÷÷÷4.5+38+40+39 =155 (people),
(4) The total number of fifth grade albums:190+171+180+234 = 775 (books),
(5) The average amount of books in fifth grade: 775÷ 155=5 (books),
So the answer is:155,775,5; 4.5; 234.