Let the vertex of this angle be A, and its two adjacent vertices are B and C, extending slightly from CA to D.
That is, ∠BAC is the inner corner ∠BAD is the outer corner.
Connect B and C to divide the original polygon into a triangle and a polygon with n- 1 sides.
Therefore: (n-1-3) *180+∠ bad+∠ ABC+∠ ACB = 600.
And ∠BAD=∠ABC+∠ACB.
So: (n-4) * 180+2 * ∠ bad = 600.
Because: 0 < 2 * ∠ bad < 360.
Therefore: 600-360 < (n-4) * 180 < 600.
So: 1.3 < n-4 < 3.4.
So: n = 6,7
When n=6, the external angle ∠ bad = 120.
When n = 7°, the external angle ∠ bad = 30.