1. The Library of Congress (Washington) has 26 million books.
2. Collection of books in Russian Library (Moscow)17.6 million volumes.
3. The National Library of China (Beijing) has a collection of books15.9 million volumes.
4. Russian Library (St. Petersburg) has a collection of books13.62 million volumes.
5. British Library (London)130,000 copies.
6. Harvard Library (Massachusetts) 1 1 10,000 volumes.
National Library of France (Paris) 1 1 10,000 volumes.
8. Leipzig Library has 9 million books.
9. The Library of Parliament of Japan (Tokyo) has 7.27 million books.
10. Frankfurt Library (Frankfurt) 7 million volumes.
I'm not sure about India's sorry.