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But the library has not yet established English.
The first library hasn't been built yet, so it can't be the third. ...

Second:

The second/third/fourth

A+ ordinal number means another, and one is added to the original one.

So this is a

Not that.

If the third library is built.

Then you can say:

I like the third library ... because it already exists.

The library in the topic does not exist, and it is still under planning. It can only be said that one third will be built soon.